Novel configurations for a citrus waste based biorefinery: from solventless to simultaneous ultrasound and microwave assisted extraction

Year: 2016

Authors: Gonzalez-Rivera J., Spepi A., Ferrari C., Duce C., Longo I., Falconieri D., Piras A., Tinè M.R.

Autors Affiliation: Univ Pisa, Dept Chem & Ind Chem, Via G Moruzzi 3, I-56124 Pisa, Italy; Natl Res Council Italy CNR, INO, Via G Moruzzi 1, I-56124 Pisa, Italy; Ist Tecn Ind Statale Michele Giua, Via Montecassino, I-09100 Cagliari, Italy; Univ Cagliari, Dept Chem & Geol Sci, Cittadella Univ Monserrato,SS 554,Km 4,500, I-09042 Monserrato, Italy.

Abstract: Innovative extraction configurations for the biorefining of a biomass waste (citrus peel) were developed in this work. Non-conventional energies, such as microwaves (MW) and ultrasounds (US), were directly irradiated to the fresh orange peel using a versatile MW coaxial dipole antenna. This particular MW configuration enabled us to build two new extraction systems: (1) a coaxial solventless MW-assisted extraction (SMWAE) approach and, (2) a simultaneous ultrasound coaxial MW-assisted hydrodistillation (US-MWHD) method. The yield and chemical composition of the essential oils (EOs) of the orange peel obtained by the two innovative approaches were analyzed as a function of the extraction time and compared with those from coaxial microwave hydrodistillation (MWHD) and conventional hydrodistillation (CH). The EOs were chemically characterized by GC and GC-MS analysis. The residue mash was then used to extract pectin by a MW-assisted procedure. The structure and thermal stability of the pectin were investigated by FTIR and TG. The biorefining of EOs and pectin from a citrus waste maximises the benefits of our proposed green methodologies, which involve safe operability, faster processing and easy scalability. Furthermore, the energy consumed per unit mass of products in each step of the orange peel biorefining clearly showed that the most promising approach is SMWAE (since it is around 27 times lower than the CH approach). MWHD and US-MWHD also showed more than 60% energy savings compared to CH.

Journal/Review: GREEN CHEMISTRY

Volume: 18 (24)      Pages from: 6482  to: 6492

More Information: This work was supported by FIRB 2012 (n.RBFR12ETL5), funded by the Italian Ministry of University and Research, and by the project PRA-2016-0046 funded by the University of Pisa. The authors would also like to thank C. Lanza, A. Barbini and F. Pardini (INO-CNR) for their valuable technical support.
KeyWords: essential oil; orange peel; thermal-analysis; plant materials; bio-refinery; pectin; hydrodistillation; green; lavender; fruit
DOI: 10.1039/c6gc02200f

ImpactFactor: 9.125
Citations: 51
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