The nu(3) band of (CO2)-C-14-O-16 molecule measured by optical-frequency-comb-assisted cavity ring-down spectroscopy
Authors: Galli I., Cancio P., Di Lonardo G., Fusina L., Giusfredi G., Mazzotti D., Tamassia F., De Natale P.
Autors Affiliation: Ist Nazl Ott CNR, I-50019 Sesto Fiorentino, FI, Italy; LENS, I-50019 Sesto Fiorentino, FI, Italy; Univ Bologna, Dipartimento Chim Fis & Inorgan, I-40136 Bologna, Italy
Abstract: The infrared spectrum of the rare isotopologue (CO2)-C-14-O-16 has been investigated in the range 2190-2250 cm(-1) with a frequency-comb-referenced cavity ring-down spectrometer. Thirty-three ro-vibrational transitions of the nu(3) fundamental band have been detected. Their absolute frequency was measured with a relative uncertainty ranging from 7.1 x 10(-8) to 1.1 x 10(-8). The experimental frequencies were fitted to the conventional Hamiltonian of a linear molecule and a new set of spectroscopic parameters for the fundamental vibrational state has been improved for this species.
Journal/Review: MOLECULAR PHYSICS
Volume: 109 (17-18) Pages from: 2267 to: 2272
More Information: This work was partially supported by Ente Cassa di Risparmio di Firenze and by Regione Toscana through the projects CTOTUS and SIMPAS, in the framework of POR-CReO FESR 2007-2013.KeyWords: Infrared spectroscopy; Molecules; Natural frequencies; Optical materials; Spectrometers; Spectroscopy, Absolute frequency; Cavity ring down; Cavity ring down spectroscopies; Experimental frequencies; Optical frequency combs; Relative uncertainty; Spectroscopic parameters; Vibrational transitions, Light measurementDOI: 10.1080/00268976.2011.614284Citations: 17data from “WEB OF SCIENCE” (of Thomson Reuters) are update at: 2019-09-15References taken from IsiWeb of Knowledge: (subscribers only)Connecting to view paper tab on IsiWeb: Click hereConnecting to view citations from IsiWeb: Click here