Scientific Results

Hyperfine effects on collisional line shape. I. A self-consistent set of equations

Year: 2011

Authors: Buffa G., Tarrini O.

Autors Affiliation: INO-CNR and Dipartimento di Fisica dell’Università, Largo Pontecorvo 3, I-56127 Pisa, Italy

Abstract: We show that the treatment available in the literature for calculating hyperfine effects on collisional line shape is affected by an error making the theory not self-consistent. By correcting such an error we show that the two hyperfine effects on the line shape, modification of the resolved components and collisional coupling between them, cancel each other when hyperfine structure collapses into a single line. (C) 2011 American Institute of Physics. [doi:10.1063/1.3585646]

Journal/Review: JOURNAL OF CHEMICAL PHYSICS

Volume: (17)      Pages from: 174309  to: 174309

KeyWords: collisional brooadening; hyperfine structure; collisional coupling
DOI: 10.1063/1.3585646

Citations: 3
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