A nanostructured hybrid material based on polymer infiltrated porous silicon layer

Year: 2010

Authors: De Stefano L., De Tommasi E., Rea I., Rotiroti L., Canciello M., Maglio G., Palumbo R.

Autors Affiliation: Institute for Microelectronic and Microsystems, National Research Council, Unit of Naples, Via P.Castellino 111, 80131 Naples, Italy; Department of Chemistry, “Federico II” University of Naples, Via Cinthia, 4-80126 Naples, Italy

Abstract: In this work, we report on the fabrication of an hybrid material based on a porous silicon (PSi) layer infiltrated by an amino functionalized poly(epsilon-caprolattone) (PCL-NH2). The organic-inorganic structure has been characterized by variable angle spectroscopic ellipsometry, optical reflectometry and water contact angle measurements. A polymer coated PSi layer, 3 mu m thick, shows improved wettability and chemical stability against long lasting, up to 18 min, exposure to an alkaline environment. Even after basic treatment, the structure still retains a very good quality optical response, so that it may be proposed as a high performance platform for biochemical sensing applications.

Journal/Review: APPLIED PHYSICS. A, MATERIALS SCIENCE & PROCESSING (PRINT)

Volume: 98 (3)      Pages from: 525  to: 530

KeyWords: Porous Silicon; Hybrid materials; Biochemical sensing
DOI: 10.1007/s00339-009-5479-5

Citations: 9
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