Investigating the Dy3+_Tb3+energy transfer dynamics in YAG ceramics and crystals

Year: 2026

Authors: Pirri A., Lapini A., Li J., Li TS., Wu LX., Liu YY., Nikl M., Pejchal J., Yoshikawa A., Toci G., Gizzi LA., Cavalli E.

Autors Affiliation: CNR, Ist Fis Applicata N Carrara, IFAC, Via Madonna Piano 10C, I-50019 Sesto Fiorentino, FI, Italy; Univ Parma, Dept Chem Sci Life & Environm Sustainabil, Parco Area Sci 11-A, I-43124 Parma, Italy; Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram, Shanghai 201899, Peoples R China; Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China; Acad Sci Czech Republ, Inst Phys, Cukrovarnicka 10, Prague 16200, Czech Republic; Tohoku Univ, Inst Mat Res, 2-1-1 Katahira, Sendai 9808577, Japan; CNR, INO, Ist Nazl Ott, Via G Moruzzi 1, I-56124 Pisa, Italy; CNR, Ist Nazl Ott, INO, Via Madonna Piano 10C, I-50019 Sesto Fiorentino, FI, Italy; Univ Parma, Dept Chem Sci Life & Environm Sustainabil, Chem Phys, Parco Area Sci 11-a, I-43124 Parma, Italy.

Abstract: A detailed study of the emission dynamics in high-optical-quality YAG ceramics singly and co-doped with Dy3+ and Tb3+ has been carried out in order to investigate the energy transfer processes between the two ions which may influence the potential of (Dy,Tb):YAG as a yellow laser medium. The excited state dynamics of Dy3+ and Tb3+ were studied at room temperature under different experimental conditions to confirm the positive effect of the Tb3+ co-doping on the Dy3+ 4F9/2 _ 6H13/2 yellow emission channel. Finally, the results obtained in YAG ceramics were compared to those obtained in YAG crystals grown by the & micro;-pulling down method with the same Dy3+ and Tb3+ co-doping levels.

Journal/Review: OPTICAL MATERIALS

Volume: 179      Pages from: 118365-1  to: 118365-11

More Information: LAG Acknowledges financial contribution from the program EuPRAXIA Preparatory Phase (No.101079773)
KeyWords: Dysprosium; Terbium; Energy transfer; Yellow laser
DOI: 10.1016/j.optmat.2026.118365