The ground state spectroscopic parameters and molecular geometry of SbH3
Anno: 1998
Autori: Fusina L., Di Lonardo G., De Natale P.
Affiliazione autori: Dipartimento di Chimica Fisica e Inorganica, Universita` di Bologna, Viale Risorgimento 4,I-40136 Bologna, Italy;
European Laboratory for Nonlinear Spectroscopy Largo E. Fermi 2, I-50125 Firenze, Italy
Abstract: The rotation spectrum of stibine; SbH3, in the ground vibrational state was recorded in the region between 30 and 100 cm(-1) at an unapodized resolution of about 0.0015 cm(-1). Delta J = +1, Delta K = 0 transitions were measured and assigned up to J\” = 15 and K = 12 for both Sb-121 arid Sb-123 isotopomers. The data of each molecule were analyzed together with the J=0, 1 rotational transitions reported in the literature, a few A(1)-A(2), K = 3 :splitting transitions and K = 1<--2, Delta K = 3 \"perturbation allowed\" transitions measured recently with Fourier transform microwave spectroscopy, and ground state combination differences from the analysis of the high resolution spectra of the stretching and bending fundamental bands. The theoretical models adopted for the analysis included Delta k = +/-3 or Delta k = +/-6 interaction terms and correspond to two different reductions of the rotational Hamiltonian. From the obtained parameters, the r(0) and the equilibrium structure were also determined for this molecule. (C) 1998 American Institute of Physics. Giornale/Rivista: JOURNAL OF CHEMICAL PHYSICS
Volume: 109 (3) Da Pagina: 997 A: 1003
Parole chiavi: Overtone band system; Stibine; Spectrum; Arsine; PH3DOI: 10.1063/1.476642Citazioni: 24dati da “WEB OF SCIENCE” (of Thomson Reuters) aggiornati al: 2024-04-28Riferimenti tratti da Isi Web of Knowledge: (solo abbonati) Link per visualizzare la scheda su IsiWeb: Clicca quiLink per visualizzare la citazioni su IsiWeb: Clicca qui