Plasmon-assisted suppression of surface trap states and enhanced band-edge emission in a bare CdTe quantum dot
Authors: Flatae A. M., Tantussi F., Messina G. C., De Angelis F., Agio M.
Autors Affiliation: Laboratory of Nano-Optics and Cμ, University of Siegen, 57072 Siegen, Germany; Istituto Italiano di Tecnologia, 16163 Genova, Italy; National Institute of Optics (INO-CNR), 50125 Florence, Italy
Abstract: Colloidal quantum dots have emerged as a versatile photoluminescent and optoelectronic material. Limitations like fluorescence intermittency, nonradiative Auger recombination, and surface traps are commonly addressed by growing a wide-band-gap shell. However, the shell isolates the excitonic wave function and reduces its interaction with the external environment necessary for different applications. Furthermore, their long emission lifetime hinders their use in high-speed optoelectronics. Here, we demonstrate a high degree of control on the photophysics of a bare core CdTe quantum dot solely by plasmon coupling, showing that more than 99% of the surface defect-state emission from a trap-rich quantum dot can be quenched. Moreover, the band-edge state excitonic and biexcitonic emission rates are Purcell enhanced by 1460- and 613-fold, respectively. Our findings show how plasmon coupling on bare quantum dots could make chemical approaches developed for improving their optical properties unnecessary, with implications for nanoscale lasers, light-emitting devices, solar cells, and ultrafast single- photon sources.
Journal/Review: THE JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume: 10 (11) Pages from: 2874 to: 2878
KeyWords: colloidal quantum dots, nanoantennas, photophysics DOI: 10.1021/acs.jpclett.9b01083Citations: 11data from “WEB OF SCIENCE” (of Thomson Reuters) are update at: 2021-10-17References taken from IsiWeb of Knowledge: (subscribers only)Connecting to view paper tab on IsiWeb: Click hereConnecting to view citations from IsiWeb: Click here